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dc.contributor.authorBonnet, Wayne
dc.contributor.otherQueen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.))en
dc.date2008-09-12 12:21:12.949en
dc.date.accessioned2008-09-15T12:35:14Z
dc.date.available2008-09-15T12:35:14Z
dc.date.issued2008-09-15T12:35:14Z
dc.identifier.urihttp://hdl.handle.net/1974/1428
dc.descriptionThesis (Master, Physics, Engineering Physics and Astronomy) -- Queen's University, 2008-09-12 12:21:12.949en
dc.description.abstractThe polymer light-emitting electrochemical cell (LEC) is an alternative method for producing electroluminescence (EL) from conjugated luminescent polymers. The in situ electrochemical doping process that leads to a dynamic p-n junction makes the devices highly insensitive to device thickness and relatively insensitive to electrode materials. These characteristics make an extremely large planar configuration accessible for observing the cross-section of the device and watching it turn on dynamically. By cooling the device to freeze ionic motion, the junction can be stabilized and photovoltaic (PV) characteristics investigated. In the planar configuration, the p-n junction was found to make up a small fraction of the inter-electrode spacing. Enabled by the insensitivity to electrode materials, small metallic particles embedded in the LEC film led to a large number of p-n junctions that could be turned on in series and parallel. This alleviates the issue of low specific emitting area suffered by planar devices and leads to improved EL effciency as well as a high open circuit voltage (Voc) when operated as a PV cell. The bulk homojunction fabrication process has been optimized by segregating the metallic particles to eliminate large aggregates. A new technique to achieve highly uniform EL from large planar LECs is also presented here. By the evaporation of a thin gold or silver film on top of an LEC, independent islands form that act as doping initiation sites across the device width. A bulk homojunction is turned on in the top layer of the LEC with a high applied bias. Island diameters and spacings are several orders of magnitude smaller than the particles in previously-reported bulk homojunction devices. Both island and particle devices had their interelectrode spacings scaled down by at least a factor of 10. The successful scaling is a promising result for the possibility of a sandwich configuration bulk homojunction device. In the case of silver island devices, cooling a 50-micron wide device after turn-on resulted in a PV cell with an open circuit voltage of 8.3 V, several times the band gap of the luminescent polymer used.en
dc.format.extent23848350 bytes
dc.format.mimetypeapplication/pdf
dc.languageenen
dc.language.isoenen
dc.relation.ispartofseriesCanadian thesesen
dc.rightsThis publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner.en
dc.subjectpolymer electronicsen
dc.subjectlight-emitting electrochemical cellsen
dc.subjectphotovoltaicen
dc.subjectsolar cellen
dc.subjectlight-emitting deviceen
dc.subjectbulk homojunctionen
dc.titleScaling and Optimization of Polymer Bulk Homojunction Light-Emitting and Photovoltaic Cellsen
dc.typeThesisen
dc.description.degreeMasteren
dc.contributor.supervisorGao, Junen
dc.contributor.departmentPhysics, Engineering Physics and Astronomyen


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