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dc.contributor.authorBarner‐Kowollik, Christopher
dc.contributor.authorBeuermann, Sabine
dc.contributor.authorBuback, Michael
dc.contributor.authorHutchinson, Robin A
dc.contributor.authorJunkers, Thomas
dc.contributor.authorKattner, Hendrik
dc.contributor.authorManders, Bart
dc.contributor.authorNikitin, Anatoly N.
dc.contributor.authorRussell, Gregory T.
dc.contributor.authorHerk, Alex M. van
dc.date.accessioned2019-09-17T18:51:17Z
dc.date.available2019-09-17T18:51:17Z
dc.date.issued2017
dc.identifier.citationBarner-Kowollik, C., Beuermann, S., Buback, M., Hutchinson, R. A., Junkers, T., Kattner, H., … van Herk, A. M. (2016). Critically Evaluated Rate Coefficients in Radical Polymerization - 8. Propagation Rate Coefficients for Vinyl Acetate in Bulk. Macromolecular Chemistry and Physics, 218(1), 1600357. doi:10.1002/macp.201600357en
dc.identifier.urihttp://hdl.handle.net/1974/26564
dc.descriptionThis is the peer reviewed version of the following article: Barner-Kowollik, C., Beuermann, S., Buback, M., Hutchinson, R. A., Junkers, T., Kattner, H., … van Herk, A. M. (2016). Critically Evaluated Rate Coefficients in Radical Polymerization - 8. Propagation Rate Coefficients for Vinyl Acetate in Bulk. Macromolecular Chemistry and Physics, 218(1), 1600357. doi:10.1002/macp.201600357, which has been published in final form at http://dx.doi.org/10.1002/macp.201600357. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en
dc.description.abstractPropagation rate coefficient values, kp, reported by several groups for radical polymerization of bulk vinyl acetate are critically evaluated. All data are obtained by the combination of pulsed-laser polymerization and subsequent polymer analysis by size exclusion chromatography, as recommended by the IUPAC Working Party on Modeling of Polymerization Kinetics and Processes. Although a small (≈15%) increase in kp is observed as laser pulse repetition rate is increased from low (25–100 Hz) to high (300–500 Hz) values, all of the data fulfill the required consistency criteria and thus are combined into a benchmark set covering the temperature range of 5–70 °C. The data are fitted well by an Arrhenius relation resulting in a pre-exponential factor of 1.35 × 107 L mol−1 s−1 and an activation energy of 20.4 kJ mol−1, with 95% confidence ellipsoids for the parameters also presented.en
dc.description.sponsorshipInternational Union of Pure and Applied Chemistry: 2013-045-1-400en
dc.publisherWileyen
dc.subjectradical polymerizationen
dc.subjectkineticsen
dc.subjectpulsed laser polymerizationen
dc.subjectvinyl acetateen
dc.titleCritically Evaluated Rate Coefficients in Radical Polymerization – 8. Propagation Rate Coefficients for Vinyl Acetate in Bulken
dc.typejournal articleen
dc.identifier.doihttps://dx.doi.org/10.1002/macp.201600357


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