Browsing Department of Chemistry Graduate Theses by Title
Now showing items 1-20 of 317
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ABC Miktoarm Star Terpolymers and Their Spherical Capsules Bearing pH-Responsive Nanochannels
(2014-10-03)This thesis reports the preparation of several ABC and ABCx miktoarm star terpolymers using a novel “assembly-and-reaction” strategy. Some of the prepared polymers were used to undergo another level of self-assembly to ... -
Achieving Bright Blue Phosphorescent Platinum(II) Compounds with Cyclometallating Phenyl-1,2,3-Triazole Ligands
Although tremendous progress has been made in the research and commercialization of organic light emitting diodes (OLEDs), the development of efficient and stable deep blue OLEDs remains one of the greatest challenges. ... -
Activation and Capture of Carbon Dioxide and Carbon Disulfide by N-Containing Compounds
(2013-12-04)The interaction between carbon dioxide (CO2) and N-compounds such as 1,8-diazobicyclo[5.4.0]undec-7-ene (DBU) has been extensively studied in the Jessop Lab. Carbon disulfide (CS2) is the sulfur congener of CO2, although ... -
Addressing Challenges in Catalysis and Energy: Selective Grafting Functionality Onto Mesoporous Silicas and Organic Hydrides for the Regeneration of Ammonia Borane, a Hydrogen Storage Material
(2011-09-12)Ordered mesoporous silicas have been shown to have a variety of useful applications ranging from adsorbents for containments to supports for catalysts. While these materials have received a good deal of attention in the ... -
The Advancement of Hadamard-Transform Excitation-Emission-Matrix Spectroscopy
A multiplexed approach to multidimensional fluorescence spectroscopy is presented. Numerous modifications were made to a home-built Hadamard-Transform Excitation-Emission Matrix (EEM) spectrometer resulting in a greatly ... -
Advances in 5-(Hydroxymethyl)Furfural Production From Cellulose Via CO2-Catalysis
The global economy must make a radical shift to lower carbon emissions to avert large-scale impacts from climate change. Fuels derived from widely available biomass such as macroalgae, have the potential to limit the CO2 ... -
Advances in Directed Ortho Metalation: Copper- and Rhodium-Catalyzed Allylic Substitution and the DMG Dance
(2015-08-13)Chapter one of this thesis describes preliminary efforts towards the development of the rhodium-catalyzed allylic arylation reaction employing nucleophiles containing ortho-DMGs (directed metalation groups). Unfortunately, ... -
Advances in Metal-Catalyzed C–H Borylation and Multicomponent Allylic Substitution Reactions
(2015-08-26)Chapter one of this thesis describes the iridium-catalyzed ortho-selective C–H borylation reaction of tertiary benzamides. An iridium(I) complex paired with an electron-deficient phosphine ligand allows for efficient C–H ... -
Advances in the synthesis of indazoles: regioselective C-7 functionalization by directed ortho metalation and progress towards indazole based azaborine compounds
As one of the fundamental heterocyclic building blocks, indazole and its derivatives have spurred significant research interest and patented applications. In particular, C-7 substituted indazole derivatives are of prime ... -
Aggregation and Redispersion of Switchable Latexes
(2011-09-26)Amidine-based switchable surfactants can be used as stabilizers during emulsion polymerization and the resulting latexes can then be destabilized by the removal of CO2. High Tg polymers have been successfully redispersed, ... -
Alternative Sample Introduction Techniques to Nebulization of Solutions in Inductively Coupled Plasma Spectrometry
The objective of this thesis was to explore alternative sample introduction techniques for inductively coupled plasma mass spectrometry (ICPMS) and optical emission spectrometry (ICPOES). This work was conducted as part ... -
Amino Acid-Type Specific Incorporation of Stable 17O Isotopes into Yeast Ubiquitin
Stable isotopic labeling is an important part of structural biology by multidimensional NMR spectroscopy. Novel stable isotopic labeling methods have continuously been developed to enhance protein NMR spectroscopy. Protein ... -
Amorphous Organic Molecular Glasses for Photovoltaic Applications
Significant progress has been achieved recently in the development of solution-processed organic photovoltaic devices, and they are now in the early stages of commercialization. However, achieving a smooth and homogenous ... -
Analysis of Potentially Toxic Bioaccessible Elements in Locally Available Bread Using Continuous On-Line Leaching Coupled to Inductively Coupled Plasma Mass Spectrometry
(2014-07-22)A previously developed, efficient and simple on-line leaching method was used to assess the bioaccessible fraction of potentially toxic elements (Cr, As, Pb and Cd) in whole wheat brown and white bread samples. Artificial ... -
Applications of Mass Spectrometry in the Studies Concerning bldA Regulation of Natural Product Biosynthesis in Streptomyces sp.
The Streptomyces are a genus of soil-dwelling Gram-positive bacteria that produce a variety of secondary metabolites; they have even been dubbed as ‘antibiotic factories’ as a typical genome can contain as many as 30 ... -
Assessment of Low Temperature Cracking in Asphalt Pavement Mixes and Rheological Performance of Asphalt Binders
(2015-04-23)Government spends a lot of money on the reconstruction and rehabilitation of road pavements in any given year due to various distresses and eventual failure. Low temperature (thermal) cracking, one of the main types of ... -
Asymmetric Homogeneous Hydrogenation of Prochiral Substrates Mediated Through Carboxylic Acid and Carbamic Acid Metal-Binding Functional Groups
(2016-01-11)The need for enantiopure chiral compounds has driven the development of asymmetric synthesis, and more specifically asymmetric catalysis. The ability to selectively produce one enantiomer versus another has been a significant ... -
Binding characterization of sulfonamide antibiotics and polycyclic aromatic hydrocarbons to micelles using semi-equilibrium dialysis (SED) and 1H NMR spectroscopy
(2016-03-30)Micellar enhanced ultrafiltration (MEUF) has been shown to be an effective removal technique for a variety of trace contaminants in wastewater, especially for low molecular weight organic contaminants. In MEUF, contaminants ... -
Biosynthesis of Fluorinated Natural Product Nucleocidin
Nucleocidin is a fluorinated adenosine analogue produced by Streptomyces calvus. It is one of only six known fluorinated natural products. The 4’-fluorine substituent on nucleocidin requires a unique two-step fluorination ...