The advent of the Suzuki–Miyaura cross–coupling reaction and its significance to the synthesis of new carbon–carbon bonds has increased the demand for efficient routes to organoboron starting materials. C–H borylation ...

The palladium-catalyzed Suzuki-Miyaura cross-coupling, in which a carbon-carbon bond is formed between an organohalide or pseudo-halide electrophile and an organoboron nucleophile, has developed into one of the most widely ...

Little attention has been given to the formation of the putative PdL2 species required for Pd-catalyzed cross-coupling reactions. Active species are generally difficult to store due to air-sensitivity and are therefore ...