Bulk luminescent solar concentrators based on organic-inorganic CH3NH3PbBr3 perovskite fluorophores
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Authors
Bagherzadeh-Khajehmarjan, Elnaz
Nikniazi, Arash
Olyaeefar, Babak
Ahmadi-Kandjani, Sohrab
Nunzi, Jean-Michel
Date
2018-12-17
Type
journal article
Language
en
Keyword
Luminescent solar concentrators , Perovskites , Solar cells , Photovoltaic conversion efficiency , Re-absorption , Monte-Carlo simulation
Alternative Title
Abstract
In this paper, we report characterization and performance results of lead bromide perovskite luminescent solar concentrator. CH3NH3PbBr3 fluorophores are synthesized by sonication method and examined by their X-ray diffraction pattern and scanning electron microscopy. Synthesized perovskite shows excitonic absorption at 524nm and PL emission peak located at 532nm with a Stokes shift around 8nm. Micron-sized fluorophores are dissolved in prepared solutions and uniformly embedded in PMMA host with 0.006% to 0.120%wt concentration. Then, Fabricated devices are cut into 50×30×5mm cuboid shapes and placed in a mirror surrounded configuration with an attached photovoltaic cell. Fabricated device is put under standard AM1.5 illumination and the output spectrum from the concentrator is acquired. Re-absorption in the samples is also measured by variable optical path method, showing red-shifts up to 13nm in the output spectrum. Spatially resolved photoluminescence maps and optical efficiencies are also presented for each sample. Plus, a Monte-Carlo ray tracing algorithm is developed to assist better understanding the experimental results. Stability of fabricated samples are evaluated under high intensity UV illumination, reporting efficiency reduction around 15% after 24 hours. Finally, Comparing current-voltage characterization of the attached photovoltaic cell reveals optimized efficiency enhancement in the 0.04%wt sample above 65%.
Description
Citation
Bagherzadeh-Khajehmarjan, E.; Nikniazi, A.; Olyaeefar, B.; Ahmadi-Kandjani, S.; Nunzi, J.-M. Bulk Luminescent Solar Concentrators Based on Organic-Inorganic CH3NH3PbBr3 Perovskite Fluorophores. Solar energy materials and solar cells 2019, 192, 44–51. https://doi.org/10.1016/j.solmat.2018.12.009.
Publisher
Elsevier