Dearomatizing and Derivatizing a Mesityl Group on Boron by One‐Pot Photoisomerization and [4+2] Diels–Alder Addition
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Authors
Deng, Billy
Wang, Xiang
Wang, Suning
Date
2019
Type
preprint
Language
en
Keyword
Arene Ligands , Boriranes , Dearomatisation , Diels-Alder Addition , Photoisomerization , Synthetic Methods
Alternative Title
Abstract
Boron compounds having a conjugated chelate backbone (N,C‐chelate or C,C‐chelate) and two mesityl substituents on boron have been found to undergo a facile one‐pot transformation/reaction with dienophiles, which leads to the dearomatization of one mesityl ring and its [4+2] Diels–Alder addition with the dienophile. Photochemical activation is the key in this transformation of the aryl ring.
Description
Citation
Publisher
Wiley
License
This is the peer reviewed version of the following article: Chem. Eur. J. 10.1002/chem.201903534, which has been published in final form at https://doi.org/10.1002/chem.201903534. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.